• 文献标题:   Natural polymer konjac glucomannan mediated assembly of graphene oxide as versatile sponges for water pollution control
  • 文献类型:   Article
  • 作  者:   CHEN T, SHI PH, ZHANG J, LI Y, DUAN T, DAI LC, WANG L, YU XF, ZHU WK
  • 作者关键词:   konjac glucomannan, graphene oxide, adsorption, uranium, malachite green
  • 出版物名称:   CARBOHYDRATE POLYMERS
  • ISSN:   0144-8617 EI 1879-1344
  • 通讯作者地址:   China Acad Engn Phys
  • 被引频次:   16
  • DOI:   10.1016/j.carbpol.2018.08.133
  • 出版年:   2018

▎ 摘  要

Three-dimensional network structure of konjac glucomannan/graphene oxide (KGM/GO) sponges was successfully prepared by ice template method. The KGM/GO sponges was rich in functional groups, negatively charged under pH 2 to 10. Batch adsorption experiment was conducted to investigate the adsorption performance of the as-prepared KGM/GO sponges for organic dye (malachite green (MG)) and radionuclide (uranium U(VI)). The results showed that the maximum adsorption capacities of KGM/GO sponges were 266.97, 189.96 mg/g for U(VI) and MG, respectively. Moreover, the KGM/GO sponges exhibited an excellent selectivity for capturing U(VI) in multi-ion system. The adsorption process was fitted better to pseudo-second order model, while adsorption isotherms for these pollutants were well matched up to Langmuir models. In addition, KGM/GO sponges can be easily separated from the aqueous solution and could be effectively reused for 5 times without obvious loss in adsorption performance. The advantages of eco-friendliness, low cost, simple preparation process, controllable shape and size, as well as high adsorption capacities for MG and U(VI), suggested that KGM/ GO sponges promising in water pollution control.