• 文献标题:   Synthesis of sandwich-like graphene@mesoporous nitrogen-doped carbon nanosheets for application in high-performance supercapacitors
  • 文献类型:   Article
  • 作  者:   CHEN Y, LIU YP, DONG YL, XIA Y, HUNG CT, LIU LL, BI W, LI W
  • 作者关键词:   mesoporous material, coating, nanosheet, graphene, supercapacitor
  • 出版物名称:   NANOTECHNOLOGY
  • ISSN:   0957-4484 EI 1361-6528
  • 通讯作者地址:   Fudan Univ
  • 被引频次:   4
  • DOI:   10.1088/1361-6528/ab4779
  • 出版年:   2020

▎ 摘  要

Nanostructured mesoporous carbon materials have been an attractive material for electrochemical energy storage in the recent decades. However, the controllable synthesis of two-dimensional mesoporous carbon with tunable thickness and desired pore structure is highly challenging. Here, a series of graphene@mesoporous nitrogen-doped carbon (denoted as G@mesoNC) core-shell structured nanosheets with tunable thicknesses have been fabricated via a sample hydrothermal method by using cellulose as the green and cheap carbon precursor. The resultant G@mesoNC nanosheets exhibit a distinct sandwich-like structure with tunable thicknesses (from 10 to 30 nm), a large surface area (562 m(2) g(-1)), a narrow pore size distribution (2.3 nm) and a high nitrogen content (7.95%). Significantly, when being used as the electrode for supercapaciors, the resultant G@mesoNC nanosheets showcase a high specific capacitance of 264 F g(-1). Most importantly, there is no substantial capacitance decay after 2500 cycles, indicating the perfect cyclic stability of G@mesoNC nanosheets. Our method paves a new way for synthesizing carbon electrodes for energy storage.