• 文献标题:   Investigation of Sr-90(II) sorption onto graphene oxides studied by macroscopic experiments and theoretical calculations
  • 文献类型:   Article
  • 作  者:   YANG SB, WANG XX, DAI SY, WANG XK, ALSHOMRANI AS, HAYAT T, AHMAD B
  • 作者关键词:   graphene oxide, sr90 ii, sorption, thermodynamic parameter, theoretical calculation
  • 出版物名称:   JOURNAL OF RADIOANALYTICAL NUCLEAR CHEMISTRY
  • ISSN:   0236-5731 EI 1588-2780
  • 通讯作者地址:   North China Elect Power Univ
  • 被引频次:   3
  • DOI:   10.1007/s10967-015-4425-6
  • 出版年:   2016

▎ 摘  要

The graphene oxides were applied as adsorbents to remove Sr-90(II) ions from aqueous solutions under different experimental conditions. The results showed that Sr-90(II) sorption was mainly dominated by ion exchange and outer-sphere surface complexation. The maximum sorption capacity (C (smas)) was calculated to be 3.84 x 10(-4) mol/g at pH 5.8 and 20 A degrees C, which was much higher than that of Sr-90(II) on other today's materials. The thermodynamic parameters suggested that the sorption was an endothermic and spontaneous process. The theoretical calculation results indicated that COH and COC groups contributed to the coordination of Sr(II) ions.