• 文献标题:   Graphene Nanosheet/Ni2+/Al3+ Layered Double-Hydroxide Composite as a Novel Electrode for a Supercapacitor
  • 文献类型:   Article
  • 作  者:   GAO Z, WANG J, LI ZS, YANG WL, WANG B, HOU MJ, HE Y, LIU Q, MANN T, YANG PP, ZHANG ML, LIU LH
  • 作者关键词:   graphene nanosheet, layered double hydroxide, composite electrode, supercapacitor
  • 出版物名称:   CHEMISTRY OF MATERIALS
  • ISSN:   0897-4756 EI 1520-5002
  • 通讯作者地址:   Harbin Engn Univ
  • 被引频次:   399
  • DOI:   10.1021/cm200975x
  • 出版年:   2011

▎ 摘  要

A hybrid chemically converted graphene nanosheet/Ni2+/Al3+ layered double-hydroxide (GNS/LDH) composite for supercapacitor material has been fabricated by a hydrothermal method. Scanning electron microscopy and transmission electron microscopy results reveal that Ni2+/Al3+ LDH platelets homogeneously grew onto the surfaces of the GNSs as spacers to keep the neighboring sheets separate. Electrochemical properties were characterized by cyclic voltammetry, galvanostatic charge/discharge measurements, and electrochemical impedance spectroscopy. The composite exhibits a maximum specific capacitance of 781.5 F/g and excellent cycle life with an increase of the specific capacitance of 38.07% after 50 cycle tests. Even after 200 cycle tests, the increase of the capacitance is 22.56% compared with the initial capacitance.