• 文献标题:   Amino-functionalized graphene oxide for Cr(VI Cu(II), Pb(II) and Cd(II) removal from industrial wastewater
  • 文献类型:   Article
  • 作  者:   HUANG HY, WANG Y, ZHANG YB, NIU ZY, LI XL
  • 作者关键词:   heavy metal, adsorption, kinetic adsorption, isotherm, industrial wastewater
  • 出版物名称:   OPEN CHEMISTRY
  • ISSN:   2391-5420
  • 通讯作者地址:   Northwest Univ
  • 被引频次:   2
  • DOI:   10.1515/chem-2020-0009
  • 出版年:   2020

▎ 摘  要

Amino-functionalized graphene oxide (GO-NH2) was synthesized by grafting (3-aminopropyl) triethoxysilane on the graphene oxide (GO) surface. The GO-NH2 with high surface area and numerous active sites can efficiently adsorb Cr(VI), Cu(II), Pb(II) and Cd(II) ions. The maximum adsorption capacities of GO-NH 2 for Cr(VI), Cu(II), Pb(II) and Cd(II) were 280.11, 26.25, 71.89 and 10.04 mg g(-1), respectively. The pseudo-first-order and pseudosecond-order kinetic models were employed to describe the kinetic processes. The experimental data agreed well with the pseudo-second-order kinetic equation, and the adsorption of heavy metals onto GO-NH2 occurs via chemical adsorption. The characteristics of Cr(VI), Cu(II), Pb(II) and Cd(II) in the GO-NH2 adsorption processes were analyzed using the Langmuir and Freundlich isotherm models. The adsorption processes of Pb(II) and Cd(II) on GO-NH2 were fit by the Langmuir model. The Freundlich isotherm model was well correlated to Cr(VI) and Cu(II). The GO-NH2 is a promising material for the removal of heavy metal ions from industrial wastewater. This study provides an effective pathway to process industrial wastewater, and the GO-NH2 has a good adsorption effect for the treatment of heavy metals in industrial wastewater.