• 文献标题:   Highly Efficient Restoration of Graphitic Structure in Graphene Oxide Using Alcohol Vapors
  • 文献类型:   Article
  • 作  者:   SU CY, XU YP, ZHANG WJ, ZHAO JW, LIU AP, TANG XH, TSAI CH, HUANG YZ, LI LJ
  • 作者关键词:   graphene oxide, raman spectroscopy, transistor, transparent conducting electrode
  • 出版物名称:   ACS NANO
  • ISSN:   1936-0851 EI 1936-086X
  • 通讯作者地址:   Acad Sinica
  • 被引频次:   179
  • DOI:   10.1021/nn101691m
  • 出版年:   2010

▎ 摘  要

Solution-based processes involving the chemical oxidation of graphite and reduction of the obtained graphene oxide (GO) sheets have attracted much attention for preparing graphene films for printed electronics and biosensors. However, the low electrical conductivity of reduced GO is still hindering the development of electronic applications. This article presents that GO sheets reduced by high-temperature alcohol vapors exhibit highly graphitic structures and excellent electrical conductivity. The sheet resistance of thin transparent films is lowered to similar to 15 k Omega/square (>96% transparency). Field-effect transistors produced from these reduced GO sheets exhibit high effective field-effect hole mobility up to 210 cm(2)/V . s. Raman spectroscopic studies reveal that the conductivity enhancement in the low mobility regime is attributed to the removal of chemical functional groups and the formation of six-fold rings. In the high mobility regime, the growth of the graphitic domain size becomes dominant for enhancing its electrical conductivity. The excellent electrical conductivity of the reduced GO sheets promises potential electronic applications.