• 文献标题:   Preparation and electrochemical performances of PEDOT/sulfonic acid-functionalized graphene composite hydrogel
  • 文献类型:   Article
  • 作  者:   HAN YQ, SHEN MX, WU Y, ZHU JJ, DING B, TONG H, ZHANG XG
  • 作者关键词:   poly 3 4ethylenedioxythiophene, graphene, composite hydrogel, electrochemical performance
  • 出版物名称:   SYNTHETIC METALS
  • ISSN:   0379-6779
  • 通讯作者地址:   Hohai Univ
  • 被引频次:   20
  • DOI:   10.1016/j.synthmet.2013.04.001
  • 出版年:   2013

▎ 摘  要

Poly(3,4-ethylenedioxythiophene) (PEDOT)/sulfonic acid-functionalized graphene composite hydrogel was prepared by introducing microcontent of sulfonic acid-functionalized graphene (SFG) using in situ polymerization. The specific capacitance of the composite hydrogel was significantly improved by the introduction of SFG when the feeding ratio of SFG to 3,4-ethylenedioxythiophene (EDOT) was as low as 1:1000, the specific capacitance of the composite hydrogel can reach 93 F/g, which was more than two times than that of the pure PEDOT hydrogel (39 F/g). The composite hydrogel showed a high specific capacitance of 135 and 220 F/g at high current density (5 A/g) when KI and K3Fe(CN)(6)-H2SO4 solution were employed as redox-active electrolytes, respectively. The composite hydrogel in K3Fe(CN)(6)-H2SO4 can be used as potential electrode material for supercapacitor applications. (c) 2013 Elsevier B.V. All rights reserved.