• 文献标题:   Conversion of uniform graphene oxide/polypyrrole composites into functionalized 3D carbon nanosheet frameworks with superior supercapacitive and sodium-ion storage properties
  • 文献类型:   Article
  • 作  者:   WANG HW, ZHANG Y, SUN WP, TAN HT, FRANKLIN JB, GUO YY, FAN HS, ULAGANATHAN M, WU XL, LUO ZZ, MADHAVI S, YAN QY
  • 作者关键词:   graphene, polypyrrole, nanosheet framework, supercapacitor, sodium ion battery
  • 出版物名称:   JOURNAL OF POWER SOURCES
  • ISSN:   0378-7753 EI 1873-2755
  • 通讯作者地址:   Nanyang Technol Univ
  • 被引频次:   16
  • DOI:   10.1016/j.jpowsour.2015.12.104
  • 出版年:   2016

▎ 摘  要

Two-dimensional (2D) graphene oxide/polypyrrole (GO/PPy) hybrid materials derived from in-situ polymerization are used as precursors for constructing functionalized three-dimensional (3D) porous nitrogen-doped carbon nanosheet frameworks (FT-PNCNFs) through a one-step activation strategy. In the formation process of FT-PNCNFs, PPY is directly converted into hierarchical porous nitrogen-doped carbon layers, while GO is simultaneously reduced to become electrically conductive. The complementary functions of individual components endow the FT-PNCNFs with excellent properties for both supercapacitors (SCs) and sodium ion batteries (SIBs) applications. When tested in symmetrical SC, the FT-PNCNFs demonstrate superior energy storage behaviour. At an extremely high scan rate of 3000 mV s(-1), the cyclic voltammetry (CV) curve retains an inspiring quasi-rectangle shape in KOH solution. Meanwhile, high capacitances (similar to 247 F g(-1) at 10 mV s(-1);-146 F g(-1) at 3000 mV s(-1)) and good cycling stability (similar to 95% retention after 8000 cycles) are achieved. In addition, an attractive SIB anode performance could be achieved. The FT-PNCNFs electrode delivers a reversible capacity of 187 mAh g(-1) during 160th cycle at 100 mA g(-1). Its reversible capacity retains 144 mAh g(-1) after extending the number of cycles to 500 at 500 mA g(-1). (C) 2015 Elsevier B.V. All rights reserved.