• 文献标题:   In situ growth of CuO nanoparticles on graphene matrix as anode material for lithium-ion batteries
  • 文献类型:   Article
  • 作  者:   QIU DF, ZHAO B, LIN ZX, PU L, PAN LJ, SHI Y
  • 作者关键词:   cuo, graphene, nanoparticle, nanocomposite, energy storage conversion, lithium ion battery
  • 出版物名称:   MATERIALS LETTERS
  • ISSN:   0167-577X EI 1873-4979
  • 通讯作者地址:   Nanjing Univ Aeronaut Astronaut
  • 被引频次:   25
  • DOI:   10.1016/j.matlet.2013.04.030
  • 出版年:   2013

▎ 摘  要

CuO nanoparticles are directly formed on graphene nanosheets through the in situ chemical decomposition of Cu(NO3)(2)center dot 3H(2)O and are anchored tightly on the graphene surface. The lithiation-induced strain is naturally accommodated, owing to the constraint effect of the graphene matrix. Electrochemical characterization shows that CuO nanoparticles anchored on graphene sample exhibits a high capacity of about 660 mAh/g at a discharge current density of 100 mA/g and a good cycling ability. During the charge-discharge process, graphene nanosheets not only served as a three-dimensional conductive network for CuO nanoparticles, but also improve the detachment and agglomeration of CuO nanoparticles. This CuO/graphene nanocomposite displays superior Li-battery performance with large reversible capacity, excellent cyclic performance, and good rate capability. (C) 2013 Elsevier B.V. All rights reserved.