• 文献标题:   Colorimetric Test Paper for H2O2 Determination Based on Peroxidase-Like Activity of an AuFe/ZIF-8-Graphene Composite
  • 文献类型:   Article
  • 作  者:   JIA SR, ZHANG XK, YUAN F, XIA T
  • 作者关键词:   graphene, metal nanoparticle, peroxidase, sensor, zif8
  • 出版物名称:   CHEMISTRYSELECT
  • ISSN:   2365-6549
  • 通讯作者地址:  
  • 被引频次:   1
  • DOI:   10.1002/slct.202202984
  • 出版年:   2022

▎ 摘  要

Herein, we prepared a bisuppport-based bimetallic nanoparticle composite AuFe/ZIF-8-graphene. It exhibited high peroxidase activity compared to those hybrids without graphene support, which demonstrated the regulatory effect of graphene on the catalytic activity. SEM, TEM, EDX, XRD, FT-IR and XPS characterization showed that Au and Fe3O4 NPs were successfully immobilized on ZIF-8-rGO carriers. Kinetic analysis confirmed that the fabricated composites showed better K-m and V-max for H2O2 than HRP and some other reported peroxidase mimics. Under the optimal conditions, a sensing assay for H2O2 determination was constructed with a linear detection range of 0.01-2.5 mM and a detection limit of 0.63 mu M. On this basis, a colorimetric test paper with its standard card was prepared for rapid visualization detection. It realized H2O2 detection in the range of 0.01-500 mM and was further successfully applicated in the semi-quantitative detection of H2O2 in actual spiked water samples. This achievement was expected to encourage the development of rapid visual detection for other pollutants in environmental and medical field.