• 文献标题:   One-pot synthesis of fluorescent nitrogen-doped graphene quantum dots for portable detection of iron ion
  • 文献类型:   Article
  • 作  者:   YAO Q, WU HY, JIN YH, WANG CL, ZHANG RT, LIN YJ, WU SJ, HU YH
  • 作者关键词:   graphene quantum dot, fluorescence, fe3+ detection, fluorescence quenching
  • 出版物名称:   CURRENT APPLIED PHYSICS
  • ISSN:   1567-1739 EI 1878-1675
  • 通讯作者地址:  
  • 被引频次:   2
  • DOI:   10.1016/j.cap.2022.05.016 EA AUG 2022
  • 出版年:   2022

▎ 摘  要

Nitrogen-doped graphene quantum dots (N-GQD) were synthesized by direct thermal decomposition of ammo-nium citrate tribasic. With the increment of torrefaction temperature, the average size of N-GQD was increased from 2.56 to 3.73 nm. Fourier transform infrared spectroscopy (FT-IR) and X-ray photoelectron spectroscopy analysis (XPS) proved the successful doping of nitrogen atoms. Besides, the N-GQDs showed blue fluorescence which was quenched by Fe3+ ions, and the fluorescence intensity of N-GQDs decayed exponentially. Accordingly, the same quenching effect was observed on a test paper prepared by soaking paper in N-GQDs dispersion. The quenching mechanism was due to electron transfer between Fe3+ and functional groups on the surface of N-GQDs which could be confirmed by XPS and diameter growth. Therefore, through this simple method, N-GQDs with high blue fluorescence and high production yield (64%) can be prepared, which provided a new strategy for monitoring and collecting Fe3+ in environmental water.