• 文献标题:   Electrical performance of orthotropic and isotropic 3YTZP composites with graphene fillers
  • 文献类型:   Article
  • 作  者:   LOPEZPERNIA C, MUNOZFERREIRO C, MORICHE R, MORALESRODRIGUEZ A, GALLARDOLOPEZ A, POYATO R
  • 作者关键词:   graphenebased nanostructures gbn, aspect ratio, zirconia, electrical conductivity, percolation threshold
  • 出版物名称:   JOURNAL OF THE EUROPEAN CERAMIC SOCIETY
  • ISSN:   0955-2219 EI 1873-619X
  • 通讯作者地址:  
  • 被引频次:   0
  • DOI:   10.1016/j.jeurceramsoc.2022.11.068 EA DEC 2022
  • 出版年:   2023

▎ 摘  要

3 mol% yttria tetragonal zirconia polycrystal (3YTZP) composites with orthotropic or isotropic microstructures were obtained incorporating few layer graphene (FLG) or exfoliated graphene nanoplatelets (e-GNP) as fillers. Electrical conductivity was studied in a wide range of contents in two configurations: perpendicular (sigma(perpendicular to)) and parallel (sigma(//)) to the pressing axis during spark plasma sintering (SPS). Isotropic e-GNP composites presented excellent electrical conductivity for high e-GNP contents (sigma(perpendicular to)similar to 3200 S/m and sigma(//) similar to 1900 S/m for 20 vol% e-GNP), consequence of their misoriented distribution throughout the matrix. Optimum electrical performance was achieved in the highly anisotropic FLG composites, with high electrical conductivity for low contents (sigma(perpendicular to) similar to 680 S/m for 5 vol%), percolation threshold below 2.5 vol% FLG and outstanding electrical conductivity for high contents (sigma(perpendicular to) similar to 4000 S/m for 20 vol%), result of the high aspect ratio and low thickness of FLG.