• 文献标题:   Construction of SnO2-Graphene Composite with Half-Supported Cluster Structure as Anode toward Superior Lithium Storage Properties
  • 文献类型:   Article
  • 作  者:   ZHU CL, CHEN ZX, ZHU SM, LI Y, PAN H, MENG X, IMTIAZ M, ZHANG D
  • 作者关键词:  
  • 出版物名称:   SCIENTIFIC REPORTS
  • ISSN:   2045-2322
  • 通讯作者地址:   Shanghai Jiao Tong Univ
  • 被引频次:   5
  • DOI:   10.1038/s41598-017-03603-1
  • 出版年:   2017

▎ 摘  要

Inspired by nature, herein we designed a novel construction of SnO2 anodes with an extremely high lithium storage performance. By utilizing small sheets of graphene oxide, the partitioned-pomegranate-like structure was constructed (SnO2@C@half-rGO), in which the porous clusters of SnO2 nanoparticles are partially supported by reduced graphene oxide sheets while the rest part is exposed (half-supported), like partitioned pomegranates. When served as anode for lithium-ion batteries, SnO2@ C@half-rGO exhibited considerably high specific capacity (1034.5 mAh g(-1) after 200 cycles at 100 mA g(-1)), superior rate performance and remarkable durability (370.3 mAh g(-1) after 10000 cycles at 5 A g(-1)). When coupled with graphitized porous carbon cathode for lithium-ion hybrid capacitors, the fabricated devices delivered a high energy density of 257 Wh kg(-1) at similar to 200 W kg(-1) and maintained 79 Wh kg(-1) at a super-high power density of similar to 20 kW kg(-1) within a wide voltage window up to 4 V. This facile and scalable approach demonstrates a new architecture for graphene-based composite for practical use in energy storage with high performance.