• 文献标题:   Comparative studies of graphene oxide and reduced graphene oxide as carbocatalysts for polymerization of 3-aminophenylboronic acid
  • 文献类型:   Article
  • 作  者:   TAN L, WANG B, FENG HX
  • 作者关键词:  
  • 出版物名称:   RSC ADVANCES
  • ISSN:   2046-2069
  • 通讯作者地址:   Lanzhou Univ Technol
  • 被引频次:   13
  • DOI:   10.1039/c2ra22516f
  • 出版年:   2013

▎ 摘  要

The use of both graphene oxide (GO) and reduced graphene oxide (RGO) as carbocatalysts for the polymerization of 3-amino-phenylboronic acid (ABA) was investigated for the first time. During the electrochemical polymerization of ABA, only RGO can effectively increase the polymerization rate due to the electronic interactions between RGO and ABA. For the in situ polymerization process, however, both RGO and GO act as molecular templates, which have a high surface area to preconcentrate ABA, so that not only is the polymerization rate increased, but also the quality of the polymer is greatly improved.