• 文献标题:   Redox synthesis of poly (p-phenylenediamine)-reduced graphene oxide for the improvement of electrochemical performance of lithium titanate in lithium-ion battery anode
  • 文献类型:   Article
  • 作  者:   RAJAGOPALAN B, KIM B, HUR SH, YOO IK, CHUNG JS
  • 作者关键词:   pphenylendiamine, reduced graphene oxide, lithium titanate, anode material, lithium ion battery
  • 出版物名称:   JOURNAL OF ALLOYS COMPOUNDS
  • ISSN:   0925-8388 EI 1873-4669
  • 通讯作者地址:   Univ Ulsan
  • 被引频次:   3
  • DOI:   10.1016/j.jallcom.2017.03.166
  • 出版年:   2017

▎ 摘  要

Poly (p-phenylenediamine)-reduced graphene oxide/lithium titanate (PpPDA-RGO)/Li4Ti5O12 (PG/LTO) nanocomposites were prepared by a simple one-step synthesis procedure using the redox reactions of a graphene oxide/LTO (GO/LTO) suspension and p-phenylenediamine (pPDA). The effect of pPDA on both the reduction of GO and the electrochemical performance in a lithium battery anode was systematically evaluated at different pPDA loadings. The rate capabilities of the PG/LTO nanocomposites were found to be superior to those of both GO/LTO and pristine LTO. Optimum electrochemical performance was ultimately obtained with a pPDA:GO ratio of 3:1. The use of pPDA increased the reduction of GO/LTO and ensured good contact between the RGO and LTO, thereby increasing the electrical conductivity of the nanocomposites. (C) 2017 Elsevier B.V. All rights reserved.