• 文献标题:   Enhancing Physicochemical Properties and Single Cell Performance of Sulfonated Poly(arylene ether) (SPAE) Membrane by Incorporation of Phosphotungstic Acid and Graphene Oxide: A Potential Electrolyte for Proton Exchange Membrane Fuel Cells
  • 文献类型:   Article
  • 作  者:   RYU SK, KIM AR, VINOTHKANNAN M, LEE KH, CHU JY, YOO DJ
  • 作者关键词:   hydrocarbon membrane, inorganic nanofiller, proton conductivity, ion cluster, pemfc
  • 出版物名称:   POLYMERS
  • ISSN:  
  • 通讯作者地址:  
  • 被引频次:   13
  • DOI:   10.3390/polym13142364
  • 出版年:   2021

▎ 摘  要

The development of potential and novel proton exchange membranes (PEMs) is imperative for the further commercialization of PEM fuel cells (PEMFCs). In this work, phosphotungstic acid (PWA) and graphene oxide (GO) were integrated into sulfonated poly(arylene ether) (SPAE) through a solution casting approach to create a potential composite membrane for PEMFC applications. Thermal stability of membranes was observed using thermogravimetric analysis (TGA), and the SPAE/GO/PWA membranes exhibited high thermal stability compared to pristine SPAE membranes, owing to the interaction between SPAEK, GO, and PWA. By using a scanning electron microscope (SEM) and atomic force microscope (AFM), we observed that GO and PWA were evenly distributed throughout the SPAE matrix. The SPAE/GO/PWA composite membrane comprising 0.7 wt% GO and 36 wt% PWA exhibited a maximum proton conductivity of 186.3 mS cm(-1) at 90 degrees C under 100% relative humidity (RH). As a result, SPAE/GO/PWA composite membrane exhibited 193.3 mW cm(-2) of the maximum power density at 70 degrees C under 100% RH in PEMFCs.