• 文献标题:   Anisotropy of functional properties of SiC composites with GNPs, GO and in-situ formed graphene
  • 文献类型:   Article, Proceedings Paper
  • 作  者:   HANZEL O, SEDLAK R, SEDLACEK J, BIZOVSKA V, BYSTRICKY R, GIRMAN V, KOVALCIKOVA A, DUSZA J, SAJGALIK P
  • 作者关键词:   graphene nanoplatelet, graphene oxide, silicon carbide, functional propertie, anisotropy
  • 出版物名称:   JOURNAL OF THE EUROPEAN CERAMIC SOCIETY
  • ISSN:   0955-2219 EI 1873-619X
  • 通讯作者地址:   Slovak Acad Sci
  • 被引频次:   11
  • DOI:   10.1016/j.jeurceramsoc.2017.03.060
  • 出版年:   2017

▎ 摘  要

This paper reports on anisotropy of functional properties of different silicon carbide-graphene composites due to preferential orientation of graphene layers during sintering. Dense silicon carbide/graphene nanoplatelets (SiC/GNPs) and silicon carbide/graphene oxide (SiC/GO) composites were sintered in the presence of yttria (Y2O3) and alumina (Al2O3) sintering additives at 1800 degrees C in vacuum by the rapid hot pressing (RHP) technique. It is found that electrical conductivity of SiC/GNPs and SiC/GO composites increases significantly in the perpendicular direction to the RHP pressing axis, reached up to 1775 S/m in the case of SiC/GO (for 3.15 wt.% of rGO). Also, thermal diffusivity was found to increase slightly by the addition of GNPs in the SiC/GNPs composites in the perpendicular direction to the RHP pressing axis. But, in the parallel direction, the addition of GNPs showed a negative effect. The formation of graphene domains was observed in reference sample SiC-Y2O3-Al2O3 sintered by RHP, without any addition of graphene. Their presence was confirmed indirectly by increasing electrical conductivity about three orders of magnitude in comparison to the reference sample sintered by conventional hot press (HP). Raman, SEM and TEM analysis were used for direct evidence of presence of graphene domains in RHP reference sample. (C) 2017 Elsevier Ltd. All rights reserved.