• 文献标题:   Graphene-Supported High-Resolution TEM and STEM Imaging of Silicon Nanocrystals and their Capping Ligands
  • 文献类型:   Article
  • 作  者:   PANTHANI MG, HESSEL CM, REID D, CASILLAS G, JOSEYACAMAN M, KORGEL BA
  • 作者关键词:  
  • 出版物名称:   JOURNAL OF PHYSICAL CHEMISTRY C
  • ISSN:   1932-7447
  • 通讯作者地址:   Univ Texas Austin
  • 被引频次:   45
  • DOI:   10.1021/jp308545q
  • 出版年:   2012

▎ 摘  要

Using graphene as an ultrathin support, high-resolution transmission and scanning transmission electron microscopy (TEM and STEM) images of organic ligand-stabilized silicon (Si) nanocrystals with unprecedented clarity were obtained. TEM images of Si nanocrystals are usually obscured on conventional amorphous carbon TEM supports because of low atomic number (Z) contrast. The atomically thin graphene supports enabled clear images of the crystalline Si cores and, for the first time, organic capping ligands. Various twin defects were observed, often accompanied by very significant lattice distortion and anisotropic strain.