• 文献标题:   Graphene oxide-assisted fabrication of mesoporous oxygen-deficient VO2 nanobelts for enhanced Zn2+ storage
  • 文献类型:   Article
  • 作  者:   LI RA, WANG L, TIAN YP, CHAO YF, CUI XW, XU Q
  • 作者关键词:   vanadium dioxide, nanocomposite, oxygen vacancy, energy storage conversion, zincion battery
  • 出版物名称:   MATERIALS LETTERS
  • ISSN:   0167-577X EI 1873-4979
  • 通讯作者地址:  
  • 被引频次:   0
  • DOI:   10.1016/j.matlet.2023.134541 EA MAY 2023
  • 出版年:   2023

▎ 摘  要

Rechargeable aqueous zinc-ion batteries (ZIBs) are regarded as promising devices for large-scale stationary en-ergy storage. However, developing ideal cathode materials confronts great challenges. Herein, a novel graphene oxide (GO)-assisted strategy is proposed to synthesis mesoporous VO2/G nanobelts with abundant oxygen defects for high-performance Zn2+ storage. The oxygen vacancies and mesopores facilitate Zn2+ insertion/extraction process. After an in-situ electrochemical activation at around 1.5 V, the monoclinic VO2 transforms to layered V2O5 center dot nH(2)O, delivering an extremely high reversible capacity of 731 mAh/g (0.1 A/g). In addition, superior high-rate and cycling performances are also achieved.