▎ 摘　　要

A multiple electrophoretic deposition (EPD) technique is developed to deposit complicated hierarchical TiO2 spheres and graphene-TiO2 spheres composite onto flexible Ti thread as working electrode of fiber-shaped dye-sensitized solar cells (F-DSSCs). Experimental results show that this multiple EPD technique cannot only fill up the cracks coming from drying the previous single EPD film but also adjust the thickness of films. More importantly, this approach is adaptable to build both single material and more complicated composite on the fiber shaped substrates. With this technique, high quality graphene-TiO2 film is acquired on flexible Ti thread and F-DSSCs based on 0.3 wt.% graphene-TiO2 hierarchical spheres show a remarkable enhancement in conversion efficiency (2.68%) compared to that of bare TiO2 hierarchical spheres (1.50%). Further TiCl4 solution treatment of 0.3 wt.% graphene-TiO2 photoanode achieves device efficiency of 3.26% resulting from the improved connectivity between the particles in the film. Our work may establish an industrial procedure to produce complex hierarchical architecture on the high curvature surface of the flexible substrates with broader range of practical application. (C) 2016 Elsevier Ltd. All rights reserved.