▎ 摘　　要

Design and preparation of carbon-based electrode material with high nitrogen-doping ratio and appropriate density attract much interest for supercapacitors in practical application. Herein; three porous carbon/graphene (NCG(Cu), NCG(Fe), and NCG(Zn)) with high doping ratio of nitrogen have been prepared via directly pyrolysis of graphene oxide (GO)/metal-organic coordination polymer (MOCP) composites, which were, formed: by reacting 4,4'-bipyridine (BPD) with CuCl2, FeCl3, and ZnCl2, respectively. As prepared NCG(Cu), NCG(Fe), and NCG(Zn) showed high nitrogen doping ratio of 10.68, 12.99, and 11.21 at. %; and high density of 1.52, 0.84, and 1.15 g cm(-3), respectively. When as-prepared samples were used as supercapacitor electrodes, NCG(Cu), NCG(Fe) and NCG(Zn), exhibited high gravimetric specific capacitances of 369, 298.5, 309.5 F g(-1), corresponding to high volumetric specific capacitances of 560.9, 250.7, 355.9 F cm(-3) at a current (tensity of 0.5 A g(-1), as well as good cycling stability, nearly 100% of the capacitance retained after 1000 cycles even at a large current density of 10 A g(-1). It is expected that the provided novel strategy can be used to develop electrode materials in high performance energy conversion/storage devices.