• 文献标题:   Flexible Boron-Doped Laser-Induced Graphene Microsupercapacitors
  • 文献类型:   Article
  • 作  者:   PENG ZW, YE RQ, MANN JA, ZAKHIDOV D, LI YL, SMALLEY PR, LIN J, TOUR JM
  • 作者关键词:   borondoped, laser induction, graphene, microsupercapacitor, flexible, porous graphene, energy storage
  • 出版物名称:   ACS NANO
  • ISSN:   1936-0851 EI 1936-086X
  • 通讯作者地址:   Univ Missouri
  • 被引频次:   177
  • DOI:   10.1021/acsnano.5b00436
  • 出版年:   2015

▎ 摘  要

Heteroatom-doped graphene materials have been intensely studied as active electrodes in energy storage devices. Here, we demonstrate that boron-doped porous graphene can be prepared in ambient air using a facile laser induction process from boric acid containing polyimide sheets. At the same time, active electrodes can be patterned for flexible microsupercapacitors. As a result of boron doping, the highest areal capacitance of as-prepared devices reaches 16.5 mF/cm(2), 3 times higher than nondoped devices, with concomitant energy density increases of 5-10 times at various power densities. The superb cyclability and mechanical flexibility of the device are well-maintained, showing great potential for future microelectronics made from this boron-doped laser-induced graphene material.