• 文献标题:   Self-assembled three-dimensional interpenetrating porous graphene aerogels with MnO2 coating and their application as high-performance supercapacitors
  • 文献类型:   Article
  • 作  者:   JI CC, XU MW, BAO SJ, LU ZJ, CAI CJ, CHAI H, WANG RY, YANG F, WEI H
  • 作者关键词:  
  • 出版物名称:   NEW JOURNAL OF CHEMISTRY
  • ISSN:   1144-0546 EI 1369-9261
  • 通讯作者地址:   Southwest Univ
  • 被引频次:   19
  • DOI:   10.1039/c3nj00599b
  • 出版年:   2013

▎ 摘  要

In this work, a hybrid materials of MnO2-wrapped graphene aerogels (GAs) were prepared using a simple in situ reduction method. The porous GAs obtained in our work not only boost ion and electron movement in electrochemical processes but can also serve as a 3D skeleton for combining with MnO2, which allows the poor electronic conductivity of MnO2 nanoparticles to be wired up to a current collector through the underlying GA conducting layers. As a supercapacitor electrode material, the structure exhibits a high reversible capacity of 210 F g(-1) at a current density of 0.5 A g(-1) with an excellent cycling retention of 99% after the 800th cycle at a current density of 2 A g(-1). These results highlight the importance of anchoring MnO2 on GAs for maximum utilization of the electrochemical activity and retaining the good electrochemical stability of the electrode materials.