• 文献标题:   Multilayer epitaxial graphene formed by pyrolysis of polycrystalline silicon-carbide grown on c-plane sapphire substrates
  • 文献类型:   Article
  • 作  者:   MCARDLE TJ, CHU JO, ZHU Y, LIU ZH, KRISHNAN M, BRESLIN CM, DIMITRAKOPOULOS C, WISNIEFF R, GRILL A
  • 作者关键词:  
  • 出版物名称:   APPLIED PHYSICS LETTERS
  • ISSN:   0003-6951 EI 1077-3118
  • 通讯作者地址:   IBM Corp
  • 被引频次:   18
  • DOI:   10.1063/1.3575202
  • 出版年:   2011

▎ 摘  要

We use ultrahigh vacuum chemical vapor deposition to grow polycrystalline silicon carbide (SiC) on c-plane sapphire wafers, which are then annealed between 1250 and 1450 degrees C in vacuum to create epitaxial multilayer graphene (MLG). Despite the surface roughness and small domain size of the polycrystalline SiC, a conformal MLG film is formed. By planarizing the SiC prior to graphene growth, a reduction in the Raman defect band is observed in the final MLG. The graphene formed on polished SiC films also demonstrates significantly more ordered layer-by-layer growth and increased carrier mobility for the same carrier density as the nonpolished samples. (C) 2011 American Institute of Physics. [doi:10.1063/1.3575202]