• 文献标题:   La0.7Ca0.3MnO3 nanoparticles anchored on N-doped graphene: Highly efficient bifunctional catalyst as counter electrode for dye-sensitized solar cells
  • 文献类型:   Article
  • 作  者:   YANG Q, ZUO XQ, YAO JX, ZHANG K, ZHANG HB, KHAN MW, WANG W, TANG HB, WU MZ, LI G, JIN SW
  • 作者关键词:   nanocomposite, dssc, counter electrode, high efficiency
  • 出版物名称:   JOURNAL OF ELECTROANALYTICAL CHEMISTRY
  • ISSN:   1572-6657 EI 1873-2569
  • 通讯作者地址:   Anhui Univ
  • 被引频次:   6
  • DOI:   10.1016/j.jelechem.2019.05.014
  • 出版年:   2019

▎ 摘  要

The composite of perovskite-phase La0.7Sr0.3MnO3 nanoparticles anchored on nitrogen-doped grapheme (LCMO@N-rGO) was synthesized via a sol-gel method followed by hydrothermal reaction, and applied in dye-sensitized solar cells (DSSCs) as efficient and low-cost counter electrodes (CEs). LCMO@N-rGO nanocomposite shows an excellent electro-catalytic activity in the reaction of I-3(-) ions to I- ions and lower charge-transfer resistance (R-ct). The power conversion efficiency (PCE) of DSSCs with LCMO@N-rGO nanocomposites as the CEs reaches 7.89%, which is much higher than that obtained with the pristine LCMO as the CEs (6.46%), and exceeds the level of Pt CEs (7.43%) under the same experimental conditions. Therefore, LCMO@N-rGO nanocomposite is expected to be an environmentally friendly, low-cost, and highly efficient CE material for DSSCs.