• 文献标题:   A graphite enclosure assisted synthesis of high-quality patterned graphene on 6H-SiC by ion implantation
  • 文献类型:   Article
  • 作  者:   CHEN YH, ZHAO YB, HAN D, FU DP, CHEN Y, ZHOU DQ, LI Y, WANG X, ZHAO ZQ
  • 作者关键词:   ion implantation, graphene, sic, graphite enclosure
  • 出版物名称:   CARBON
  • ISSN:   0008-6223 EI 1873-3891
  • 通讯作者地址:  
  • 被引频次:   5
  • DOI:   10.1016/j.carbon.2020.09.083
  • 出版年:   2021

▎ 摘  要

Synthesis of high-quality graphene on insulating/semiconducting substrate is important in the development of future graphene-based electronic device technology. In this paper, an approach of ion implantation followed by annealing in a graphite enclosure was used to directly produce high-quality patterned graphene on 6H-SiC. Specifically, 5 keV argon ions were implanted in single-crystal 6H-SiC followed by thermal annealing in a graphite enclosure to synthesize graphene using the graphite enclosure as a carbon source. After annealing, carbon atoms, coming from graphite enclosure and SiC itself, migrate to the substrate surface and self-assemble into graphene. In contrast with present graphene production techniques, our approach requires a significantly lower temperature of similar to 1100 degrees C and avoids the use of a large amount of gases, hydrogen etching and transfer process. Moreover, in this approach, patterned graphene can be synthesized by precisely controlling the growth site. To understand the growth mechanism, a brief model based on the influence of ion implantation, heat preservation time and graphite enclosure was established. Our work has established a convenient and economical approach of graphene production and expects to spark more interest in graphene-based electronic devices. (C) 2020 Elsevier Ltd. All rights reserved.