• 文献标题:   Mo (CO)(6)-assisted Pd-supported magnetic graphene oxide-catalyzed carbonylation-cyclization as an efficient way for the synthesis of 4(3H)-quinazolinones
  • 文献类型:   Article
  • 作  者:   BAHADORIKHALILI S, ANSARI S, HAMEDIFAR H, MA MANI L, BABAEI M, EQRA R, MAHDAVI M
  • 作者关键词:   carbonyl insertion, magnetic graphene oxide, molybdenum hexacarbonyl, palladium catalyst, quinazolinone
  • 出版物名称:   APPLIED ORGANOMETALLIC CHEMISTRY
  • ISSN:   0268-2605 EI 1099-0739
  • 通讯作者地址:   Alborz Univ Med Sci
  • 被引频次:   3
  • DOI:   10.1002/aoc.4769
  • 出版年:   2019

▎ 摘  要

In this paper, a novel catalyst is introduced based on the immobilization of palladium on modified magnetic graphene oxide nanoparticles. The catalyst is characterized by several methods, including transmission electron microscopy, scanning electron microscopy, X-ray fluorescence, vibrating-sample magnetometer, Fourier transform-infrared and dynamic light scattering (DLS) analysis. The activity of the catalyst was investigated in the synthesis of 4(3H)-quinazolinones via Pd-catalyzed carbonylation-cyclization of N-(2-bromoaryl) benzimidamides by Mo (CO)(6). The Mo (CO)(6) is used as a carbon monoxide source for performing the reaction under mild conditions. The catalyst showed good reusability, and no change in activity was observed after 10 cycles of recovery.