• 文献标题:   Organic Radical-Assisted Electrochemical Exfoliation for the Scalable Production of High-Quality Graphene
  • 文献类型:   Article
  • 作  者:   YANG S, BRULLER S, WU ZS, LIU ZY, PARVEZ K, DONG RH, RICHARD F, SAMORI P, FENG XL, MULLEN K
  • 作者关键词:  
  • 出版物名称:   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
  • ISSN:   0002-7863
  • 通讯作者地址:   Tech Univ Dresden
  • 被引频次:   122
  • DOI:   10.1021/jacs.5b09000
  • 出版年:   2015

▎ 摘  要

Despite the intensive research efforts devoted to graphene fabrication over the past decade, the production of high-quality graphene on a large scale, at an affordable cost, and in a reproducible manner still represents a great challenge. Here, we report a novel method based on the controlled electrochemical exfoliation of graphite in aqueous ammonium sulfate electrolyte to produce graphene in large quantities and with outstanding quality. Because the radicals (e.g., HO center dot) generated from water electrolysis are responsible for defect formation on graphene during electrochemical exfoliation, a series of reducing agents as additives (e.g., (2,2,6,6-tetramethylpiperidin-1-yl) oxyl (TEMPO), ascorbic acid, and sodium borohydride) have been investigated to eliminate these radicals and thus control the exfoliation process. Remarkably, TEMPO-assisted exfoliation results in large graphene sheets (5-10 mu m on average), which exhibit outstanding hole mobilities (similar to 405 cm(2) V-1 s(-1)), very low Raman I-D/I-G ratios (below 0.1), and extremely high carbon to oxygen (C/O) ratios (similar to 25.3). Moreover, the graphene ink prepared in dimethylformamide can exhibit concentrations as high as 6 mg mL(-1) thus qualifying this material for intriguing applications such as transparent conductive films and flexible supercapacitors. In general, this robust method for electrochemical exfoliation of graphite offers great promise for the preparation of graphene that can be utilized in industrial applications to create integrated nanocomposites, conductive or mechanical additives, as well as energy storage and conversion devices.