• 文献标题:   Facile and rapid decoration of graphene oxide with copper double salt, oxides and metallic copper as catalysts in oxidation and coupling reactions
  • 文献类型:   Article
  • 作  者:   SHABESTARI ME, MARTIN O, DIAZGARCIA D, GOMEZRUIZ S, GONZALEZ VJ, BASELGA J
  • 作者关键词:  
  • 出版物名称:   CARBON
  • ISSN:   0008-6223 EI 1873-3891
  • 通讯作者地址:   Carlos III Univ Madrid
  • 被引频次:   2
  • DOI:   10.1016/j.carbon.2020.01.015
  • 出版年:   2020

▎ 摘  要

We present a new facile and rapid microwave-assisted method to synthesize four different copper nanocompounds on the surface of graphene oxide (GO). By starting from a mixture of copper nitrate and GO, copper hydroxy nitrate double salt (DS) (Cu-2(OH)(3)(NO3)), copper (II) and copper (I) oxides and metallic copper (Cu-0) were synthesized and supported simultaneously. The catalytic performance of the four copper/GO nanohybrids as well as some unsupported particles in some common organic reactions has been checked. The studied materials present a high versatility in C-C, C-N, and C-S couplings as well as in catalytic selective oxidation reactions. The performance of DS/GO as an heterogeneous catalyst is presented for the first time and shows the highest activity among all the copper/GO nanohybrid studied systems. The results open up the possibility of a more thorough study of the catalytic performance of the supported copper double salt in other different catalytic and consecutive processes of organic synthesis. (C) 2020 Elsevier Ltd. All rights reserved.