• 文献标题:   Heterogeneous Fluorescence Intermittency in Single Layer Reduced Graphene Oxide
  • 文献类型:   Article
  • 作  者:   SI JX, VOLKANKACSO S, ELTOM A, MOROZOV Y, MCDONALD MP, KUNO M, JANKO B
  • 作者关键词:   fluorescence intermittency, graphene oxide, heterogeneity, mrc model
  • 出版物名称:   NANO LETTERS
  • ISSN:   1530-6984 EI 1530-6992
  • 通讯作者地址:   Univ Notre Dame
  • 被引频次:   6
  • DOI:   10.1021/acs.nanolett.5b00191
  • 出版年:   2015

▎ 摘  要

We provide, for the first time, direct experimental evidence for heterogeneous blinking in reduced graphene oxide (rGO) during photolysis. The spatially resolved intermittency originates from regions within individual rGO sheets and shows 1/Pike power spectral density. We describe the evolution of rGO blinking using the multiple recombination center (MRC) model that captures common features of nanoscale blinking. Our results illustrate the universal nature of blinking and suggest a common microscopic origin for the effect.