• 文献标题:   Mechanotunable monatomic metal structures at graphene edges
  • 文献类型:   Article
  • 作  者:   WEI N, CHANG C, ZHU HW, XU ZP
  • 作者关键词:  
  • 出版物名称:   PHYSICAL CHEMISTRY CHEMICAL PHYSICS
  • ISSN:   1463-9076 EI 1463-9084
  • 通讯作者地址:   Tsinghua Univ
  • 被引频次:   2
  • DOI:   10.1039/c3cp55063j
  • 出版年:   2014

▎ 摘  要

Monatomic metal (e.g. silver) structures could form preferably at graphene edges. We explore their structural and electronic properties by performing density functional theory based first-principles calculations. The results show that cohesion between metal atoms, as well as electronic coupling between metal atoms and graphene edges offer remarkable structural stability of the hybrid. We find that the outstanding mechanical properties of graphene allow tunable properties of the metal monatomic structures by straining the structure. The concept is extended to metal rings and helices that form at open ends of carbon nanotubes and edges of twisted graphene ribbons. These findings demonstrate the role of graphene edges as an efficient one-dimensional template for low-dimensional metal structures that are mechanotunable.