• 文献标题:   Graphene nanocomposites of CdS and ZnS in effective water purification
  • 文献类型:   Article
  • 作  者:   SAHOO AK, SRIVASTAVA SK, RAUL PK, GUPTA AK, SHRIVASTAVA R
  • 作者关键词:   cds/graphene, zns/graphene, heavy metal removal, water purification
  • 出版物名称:   JOURNAL OF NANOPARTICLE RESEARCH
  • ISSN:   1388-0764 EI 1572-896X
  • 通讯作者地址:   Indian Inst Technol
  • 被引频次:   11
  • DOI:   10.1007/s11051-014-2473-4
  • 出版年:   2014

▎ 摘  要

The present work deals with syntheses of CdS/graphene and ZnS/graphene nanocomposites by hydrothermal reaction of graphene oxide and morpholine-4-carbodithioate complex of Cd and Zn, respectively. The corresponding nanocomposites has been investigated separately as photocatalyst in the decomposition of methylene blue in the presence of UV light and also as adsorbents in the removal of Cd(II) and Pb(II) ions in contaminated water. These studies have established that CdS/graphene and ZnS/graphene are effective photocatalyst as well as effective adsorbents in the removal of Cd(II) and Pb(II) ions to an extent of 97 and 99 % by ZnS/graphene and CdS/graphene nanocomposite, respectively, under 1 g L-1 of adsorption dose and at pH similar to 7. Further studies also established Langmuir model befitting for the adsorption of Pb(II) and Cd(II) ions on CdS/graphene and ZnS/graphene, respectively. The presence of interfering ions on extent of Cd(II) and Pb(II) removal has also been reported.