• 文献标题:   Nitrogen-doped graphene quantum dots coated with molecularly imprinted polymers as a fluorescent sensor for selective determination of warfarin
  • 文献类型:   Article
  • 作  者:   LI PP, DU YX, MA MX, ZHANG J
  • 作者关键词:  
  • 出版物名称:   NEW JOURNAL OF CHEMISTRY
  • ISSN:   1144-0546 EI 1369-9261
  • 通讯作者地址:  
  • 被引频次:   4
  • DOI:   10.1039/d2nj00853j EA APR 2022
  • 出版年:   2022

▎ 摘  要

Water-soluble and eco-friendly nitrogen-doped graphene quantum dots (NGQDs) were synthesized via a hydrothermal method. Subsequently, a novel optical sensor based on NGQDs coated with molecularly imprinted polymers (NGQDs@MIPs) was prepared via sol-gel polymerization. The synthesized polymers were characterized by transmission electron microscopy, X-ray diffraction, thermogravimetric analysis, and Fourier transform infrared spectroscopy. The NGQDs@MIPs sensor showed specific selectivity and superior detection performance for warfarin which is a common anticoagulant rodenticide in environmental samples. The fluorescence intensity of the NGQDs@MIPs sensor presented an excellent linear response with warfarin concentrations ranging from 0.63 mu M to 10 mu M with a 0.16 mu M detection limit. The recovery of warfarin from spiked environmental samples varied from 94.38% to 105.84%, with a relative standard deviation of less than 5.0%. Therefore, the NGQDs@MIPs sensor with a selective response and remarkable anti-interference performance may be a feasible method for the rapid detection of warfarin in environmental samples.