• 文献标题:   Graphene oxide/Fe3O4/SO3H nanohybrid: a new adsorbent for adsorption and reduction of Cr(VI) from aqueous solutions
  • 文献类型:   Article
  • 作  者:   ALIZADEH A, ABDI G, KHODAEI MM, ASHOKKUMAR M, AMIRIAN J
  • 作者关键词:  
  • 出版物名称:   RSC ADVANCES
  • ISSN:   2046-2069
  • 通讯作者地址:   Razi Univ
  • 被引频次:   22
  • DOI:   10.1039/c7ra01536d
  • 出版年:   2017

▎ 摘  要

A sulfonated magnetic graphene oxide (SMGO) hybrid was successfully synthesized via the nucleophilic substitution reaction and characterized. The removal of chromate by SMGO was investigated. The effects of contact time, initial pH of the solution, and initial chromate concentration on the removal efficiency were investigated. The optimal experimental conditions for enhanced chromate removal were found to be a contact time of 60 min at an initial solution pH of 3. The observed data were fitted with Lagergren pseudo-second-order kinetic model, indicating that chromate adsorption on SMGO was a chemical interaction in nature. The Langmuir model was also used to describe the adsorption processes and the adsorption capacity was found to be 222.22 mg g (1). Thermodynamic studies (triangle G < 0, triangle H > 0, triangle S > 0) revealed that the adsorption process was exothermic and spontaneous. SMGO has potential to be applied several times after desorption in wastewater treatment.