• 文献标题:   Electrodeposition of Manganese-Nickel-Cobalt Sulfides on Reduced Graphene Oxide/Nickel Foam for High-Performance Asymmetric Supercapacitors
  • 文献类型:   Article
  • 作  者:   EVARISTE U, JIANG GH, YU B, LIU YK, MA PP
  • 作者关键词:   ternary metal sulfide, electrochemical, asymmetric supercapacitor, energy storage
  • 出版物名称:   JOURNAL OF ELECTRONIC MATERIALS
  • ISSN:   0361-5235 EI 1543-186X
  • 通讯作者地址:   Natl Engn Lab Text Fiber Mat
  • 被引频次:   4
  • DOI:   10.1007/s11664-019-07810-6
  • 出版年:   2020

▎ 摘  要

Ternary metal sulfides are potential and attractive materials for supercapacitors. Manganese-nickel-cobalt ternary sulfide (MNCS) nanosheets deposited on reduced graphene oxide/nickel foam (rGO/NF) have been synthesized via a simple electrochemical approach. The obtained ternary metal sulfide (MNCS@rGO/NF) showed better electrochemical performance than corresponding bimetal nickel-cobalt sulfides on reduced graphene oxide/nickel foam (NCS@rGO/NF), which can be attributed to the addition of manganese to increase the oxidation state in the electrodes. The MNCS@rGO/NF electrode material achieved a significant specific capacitance of 1302 F g(-1) at 0.5 A g(-1), with good rate performance and cyclic stability. In addition, asymmetric supercapacitor devices using the MNCS@rGO/NF and rGO/NF as positive and negative electrodes were fabricated, delivering high energy density of 103.62 Wh kg(-1) at power density of 562.47 W kg(-1) and 39.93 Wh kg(-1) at power density of 1514.78 W kg(-1).