• 文献标题:   Mid-IR reflectance spectrum of multilayer graphene: Influence of adsorbate at the graphene - substrate interface
  • 文献类型:   Article
  • 作  者:   FROLOV VD, PIVOVAROV PA, PLOTNICHENKO VG, KONOV VI
  • 作者关键词:   graphene, optical propertie, ir spectroscopy, water adsorbate
  • 出版物名称:   QUANTUM ELECTRONICS
  • ISSN:   1063-7818 EI 1468-4799
  • 通讯作者地址:   Russian Acad Sci
  • 被引频次:   0
  • DOI:   10.1070/QEL17088
  • 出版年:   2019

▎ 摘  要

Water adsorbate at the interface between graphene and SiO2/Si substrate is found to affect the reflectance spectra of (3 - 6)-layer graphene in the mid-IR range (lambda = 2 - 16 mu m). The sample under study was previously kept in acetone vapour to remove water adsorbate from the graphene - substrate interface. The graphene reflectance in the range of 8 - 16 mu m tends to decrease with recovery of water adsorbate layer at the graphene - substrate interface at room temperature and relative air humidity RH = 40% - 60%. The observed effect is most likely caused by the blue shift of the absorption edge at interband transitions due to the change in the Fermi level position in the graphene valence band under the influence of the charge induced in graphene by the water adsorbate film.