• 文献标题:   The Influence of Out-of-Plane Deformation on the Band Gap of Graphene Nanoribbons
  • 文献类型:   Article
  • 作  者:   ZHANG J, ONG KP, WU P
  • 作者关键词:  
  • 出版物名称:   JOURNAL OF PHYSICAL CHEMISTRY C
  • ISSN:   1932-7447
  • 通讯作者地址:   Inst High Performance Comp
  • 被引频次:   18
  • DOI:   10.1021/jp103195u
  • 出版年:   2010

▎ 摘  要

We performed ab initio calculations to study the effect of out-of-plane deformation on the electronic structures of graphene nanoribbons. We find that the band gap of severely curved GNR is significantly modified and a semiconductor-metal transition can be observed under the radial deformation. The band gap changes mainly arise from the hybridization of sigma and pi orbitals and the modification of orbital interactions. It is possible that good geometry control can result in semiconductor-metal transition in deformed graphene nanoribbons.