• 文献标题:   Facile synthesis of graphene nanoplate-supported porous Pt-Cu alloys with high electrocatalytic properties for methanol oxidation
  • 文献类型:   Article
  • 作  者:   ZHANG GL, YANG ZZ, ZHANG W, WANG YX
  • 作者关键词:  
  • 出版物名称:   JOURNAL OF MATERIALS CHEMISTRY A
  • ISSN:   2050-7488 EI 2050-7496
  • 通讯作者地址:   Tianjin Univ
  • 被引频次:   17
  • DOI:   10.1039/c5ta09937d
  • 出版年:   2016

▎ 摘  要

In this work, a simple and facile aqueous solution method was developed for the synthesis of uniform porous Pt-Cu nanocrystals (NCs) supported on 1-aminopyrene functionalized graphene nanoplates (p-Pt-Cu/AP-GNPs), without any high boiling point organic solvents, surfactants, stabilizers and templates. The as-prepared p-Pt-Cu/AP-GNP catalysts exhibit superior electrocatalytic activities and stabilities for methanol oxidation under alkaline conditions compared to Pt/AP-GNPs and Pt/C-JM, and the electrocatalytic performance varies with the relative content of Pt and Cu with the p-Pt1Cu1/AP-GNP catalyst topping all p-Pt-Cu/AP-GNP catalysts studied. This strategy may open a new route to design and prepare superior electrocatalysts for fuel cells.