• 文献标题:   Ferrocene-functionalized graphene electrode for biosensing applications
  • 文献类型:   Article
  • 作  者:   RABTI A, MAYORGAMARTINEZ CC, BAPTISTAPIRES L, RAOUAFI N, MERKOCI A
  • 作者关键词:   reduced graphene oxide electrode, functionalization, ferrocene, nonenzymatic sensor, biosensor
  • 出版物名称:   ANALYTICA CHIMICA ACTA
  • ISSN:   0003-2670 EI 1873-4324
  • 通讯作者地址:   CSIC
  • 被引频次:   24
  • DOI:   10.1016/j.aca.2016.04.010
  • 出版年:   2016

▎ 摘  要

A novel ferrocene-functionalized reduced graphene oxide (rGO)-based electrode is proposed. It was fabricated by the drop casting of ferrocene-functionalized graphene onto polyester substrate as the working electrode integrated within screen-printed reference and counter electrodes. The ferrocene-functionalized rGO has been fully characterized using FTIR, XPS, contact angle measurements, SEM and TEM microscopy, and cyclic voltammetry. The XPS and EDX analysis showed the presence of Fe element related to the introduced ferrocene groups, which is confirmed by a clear CV signal at ca. 0.25 V vs. Ag/AgCl (0.1 KCl). Mediated redox catalysis of H2O2 and bio-functionalization with glucose oxidase for glucose detection were achieved by the bioelectrode providing a proof for potential biosensing applications. (C) 2016 Elsevier B.V. All rights reserved.