• 文献标题:   Sensitive photo-thermal response of graphene oxide for mid-infrared detection
  • 文献类型:   Article
  • 作  者:   BAE JJ, YOON JH, JEONG S, MOON BH, HAN JT, JEONG HJ, LEE GW, HWANG HR, LEE YH, JEONG SY, LIM SC
  • 作者关键词:  
  • 出版物名称:   NANOSCALE
  • ISSN:   2040-3364 EI 2040-3372
  • 通讯作者地址:   Korea Electrotechnol Res Inst
  • 被引频次:   22
  • DOI:   10.1039/c5nr04039f
  • 出版年:   2015

▎ 摘  要

This study characterizes the effects of incident infrared (IR) radiation on the electrical conductivity of graphene oxide (GO) and examines its potential for mid-IR detection. Analysis of the mildly reduced GO (m-GO) transport mechanism near room temperature reveals variable range hopping (VRH) for the conduction of electrons. This VRH behavior causes the m-GO resistance to exhibit a strong temperature dependence, with a large negative temperature coefficient of resistance of approximately -2 to -4% K-1. In addition to this hopping transport, the presence of various oxygen-related functional groups within GO enhances the absorption of IR radiation significantly. These two GO material properties are synergically coupled and provoke a remarkable photothermal effect within this material; specifically, a large resistance drop is exhibited by m-GO in response to the increase in temperature caused by the IR absorption. The m-GO bolometer effect identified in this study is different from that exhibited in vanadium oxides, which require added gold-black films that function as IR absorbers owing to their limited IR absorption capability.