• 文献标题:   TiO2/NiO/reduced graphene oxide nanocomposites as anode materials for high-performance lithium ion batteries
  • 文献类型:   Article
  • 作  者:   CHEN ZH, GAO Y, ZHANG QX, LI LL, MA PC, XING BL, CAO JL, SUN G, BALA H, ZHANG CX, ZHANG ZY, ZENG YY
  • 作者关键词:   tio2/nio, rgo, anode material, lithiumion battery
  • 出版物名称:   JOURNAL OF ALLOYS COMPOUNDS
  • ISSN:   0925-8388 EI 1873-4669
  • 通讯作者地址:   Henan Polytech Univ
  • 被引频次:   8
  • DOI:   10.1016/j.jallcom.2018.10.010
  • 出版年:   2019

▎ 摘  要

In this study, NiO was synthesized via a facile method and coated on the surface of a TiO2 anode material doped with rGO (reduced graphene oxide). TiO2/NiO/rGO nanocomposite structures were synthesized by a two-step solid-state method, and their lithium storage capacity was investigated and compared with that of both as-prepared TiO2/NiO and pure TiO2. The coating over the TiO2 surface helped to attain a higher capacity and cycle stability than that without it, even at high current rates. The TiO2/NiO/rGO nanocomposites show excellent performance with an initial discharge capacity of up to 324 mAh/g between 0 and 3 V vs Li at 20 mA/g. Furthermore, at a high current density of 100 mA/g, the TiO2/NiO/rGO nanocomposite still achieved a capacity of 245 mAh/g after 200 cycles. This excellent performance could be attributed to the stable framework and high electronic conductivity within the TiO2/NiO/rGO nanocomposite. (C) 2018 Elsevier B.V. All rights reserved.