• 文献标题:   Thermal and electrical properties enhancement of a nanocomposite of industrial silicone rubber filled with reduced graphene oxide
  • 文献类型:   Article
  • 作  者:   SORIANOORTIZ JA, RUEDAMORALES G, MARTINEZGUITIERREZ H, ROJASTRIGOS JB, ORTEGACERVANTEZ G, ORTIZLOPEZ J
  • 作者关键词:   nanocomposite, reduced graphene oxide, industrial silicone rubber, thermal conductivity, electrical resistivity
  • 出版物名称:   FULLERENES NANOTUBES CARBON NANOSTRUCTURES
  • ISSN:   1536-383X EI 1536-4046
  • 通讯作者地址:  
  • 被引频次:   1
  • DOI:   10.1080/1536383X.2021.1929189 EA MAY 2021
  • 出版年:   2022

▎ 摘  要

In this work, a nanocomposite was developed by in-situ polymerization using industrial-grade diatom-containing silicone rubber (SR) as the matrix and reduced graphene oxide (RGO) as filler. The Concentration of RGO, was very low, varying from 0 to 1 wt%. In these nanocomposites, diatoms as well as RGO flakes of sizes smaller than 20 mu m were dispersed homogeneously within the SR. According to thermogravimetric analysis (TGA), the thermal stability of the composite is improved by increasing the decomposition temperature of SR from 497 degrees C to 546 degrees C at 0.8 wt% of RGO. A TGA signal between 620 degrees C and 670 degrees C is identified as due to C-C bonds thermal breaking, whose integrated intensity increases in proportion to the concentration of RGO and can be used to determine the concentration of RGO in similar composite systems. When 1.0 wt% of RGO is added thermal conductivity increases by 47.5% and the electrical resistivity decreases four orders of magnitude, respect to SR values. The SR/RGO nanocomposite is flexible and represents a good candidate for applications in the development of sensors and biomedical applications. The use of industrial-grade SR reduces production costs of composites in comparison to those prepared with more expensive analytical grade rubbers.