• 文献标题:   Cobalt-doped ZnS-reduced graphene oxide nanocomposite as an advanced photocatalytic material
  • 文献类型:   Article
  • 作  者:   AGORKU ES, MAMO MA, MAMBA BB, PANDEY AC, MISHRA AK
  • 作者关键词:   graphene, cobalt, zns, indigo carmine, photocatalysi
  • 出版物名称:   JOURNAL OF POROUS MATERIALS
  • ISSN:   1380-2224 EI 1573-4854
  • 通讯作者地址:   Univ Johannesburg
  • 被引频次:   15
  • DOI:   10.1007/s10934-014-9871-y
  • 出版年:   2015

▎ 摘  要

The removal of toxic organic pollutants from wastewater by graphene-based photocatalysts has dominated recent scientific research. As a result numerous nanomaterials have been studied and used for water remediation. ZnS has been widely studied due to its versatile application in photocatalysis. This study presents the synthesis of Co-doped graphene-ZnS nanocomposite by co-precipitation method. The materials were characterized by X-ray diffraction , Raman spectroscopy, Fourier transform infrared spectroscopy, scanning electron microscopy, transmission electron microscopy and Brunauer-Emmett-Teller surface area analysis. UV/Vis diffuse reflectance spectroscopy was employed to estimate band gap energies. Laboratory experiments with indigo carmine (IC) dye was chosen as a model for organic pollutants and was used to evaluate the photocatalytic performance of Co-doped ZnS-rGO nanocomposite under visible light. The Co-doped ZnS-rGO showed significant visible light induced photocatalytic activity towards the degradation of IC. Highest photocatalytic activity was observed for the 0.3 % Co-doped ZnS-rGO sample (k = 3.1 x 10(-2) min(-1)).