• 文献标题:   A facile way to produce epoxy nanocomposites having excellent thermal conductivity with low contents of reduced graphene oxide
  • 文献类型:   Article
  • 作  者:   OLOWOJOBA GB, KOPSIDAS S, ESLAVA S, GUTIERREZ ES, KINLOCH AJ, MATTEVI C, ROCHA VG, TAYLOR AC
  • 作者关键词:  
  • 出版物名称:   JOURNAL OF MATERIALS SCIENCE
  • ISSN:   0022-2461 EI 1573-4803
  • 通讯作者地址:   Imperial Coll London
  • 被引频次:   23
  • DOI:   10.1007/s10853-017-0969-x
  • 出版年:   2017

▎ 摘  要

A well-dispersed phase of exfoliated graphene oxide (GO) nanosheets was initially prepared in water. This was concentrated by centrifugation and was mixed with a liquid epoxy resin. The remaining water was removed by evaporation, leaving a GO dispersion in epoxy resin. A stoichiometric amount of an anhydride curing agent was added to this epoxy-resin mixture containing the GO nanosheets, which was then cured at 90 A degrees C for 1 h followed by 160 A degrees C for 2 h. A second thermal treatment step of 200 A degrees C for 30 min was then undertaken to reduce further the GO in situ in the epoxy nanocomposite. An examination of the morphology of such nanocomposites containing reduced graphene oxide (rGO) revealed that a very good dispersion of rGO was achieved throughout the epoxy polymer. Various thermal and mechanical properties of the epoxy nanocomposites were measured, and the most noteworthy finding was a remarkable increase in the thermal conductivity when relatively very low contents of rGO were present. For example, a value of 0.25 W/mK was measured at 30 A degrees C for the nanocomposite with merely 0.06 weight percentage (wt%) of rGO present, which represents an increase of similar to 40% compared with that of the unmodified epoxy polymer. This value represents one of the largest increases in the thermal conductivity per wt% of added rGO yet reported. These observations have been attributed to the excellent dispersion of rGO achieved in these nanocomposites made via this facile production method. The present results show that it is now possible to tune the properties of an epoxy polymer with a simple and viable method of GO addition.