• 文献标题:   Electrocatalytic Oxidation and Determination of Hydrazine at an AuCu Nanoparticles - Graphene - Ionic Liquid Composite Film Coated Glassy Carbon Electrode
  • 文献类型:   Article
  • 作  者:   SHANG L, ZHAO FQ, ZENG BZ
  • 作者关键词:   aucu nanoparticle, graphene, electrodeposition, hydrazine, ionic liquid
  • 出版物名称:   ELECTROANALYSIS
  • ISSN:   1040-0397 EI 1521-4109
  • 通讯作者地址:   Wuhan Univ
  • 被引频次:   14
  • DOI:   10.1002/elan.201200209
  • 出版年:   2012

▎ 摘  要

Gold-copper alloy nanoparticles (AuCu NPs) were electrodeposited on a graphene ionic liquid composite film (EGN-IL). The AuCu NPs showed high electrocatalysis to the oxidation of hydrazine with a catalytic reaction rate constant of about 5.0x104 mol/Ls. In phosphate buffer solutions (pH 6.8) the oxidation current of hydrazine at 0.15 V (vs. SCE) at the resulting electrode (AuCu?EGN-IL/GCE) was linear to its concentration in the range of 0.2110 mu M with a sensitivity of 56.7 mu A/mM, and the detection limit was 0.1 mu M (S/N=3). The electrode was successfully applied to the determination of waste water.