• 文献标题:   Composite materials of graphene nanoplatelets and polypropylene, prepared by in situ polymerization
  • 文献类型:   Article
  • 作  者:   POLSCHIKOV SV, NEDOREZOVA PM, KLYAMKINA AN, KOVALCHUK AA, ALADYSHEV AM, SHCHEGOLIKHIN AN, SHEVCHENKO VG, MURADYAN VE
  • 作者关键词:   nanocomposite, graphene nanoplatelet, poly propylene, metallocene catalyst
  • 出版物名称:   JOURNAL OF APPLIED POLYMER SCIENCE
  • ISSN:   0021-8995
  • 通讯作者地址:   Russian Acad Sci
  • 被引频次:   40
  • DOI:   10.1002/app.37837
  • 出版年:   2013

▎ 摘  要

Nanocomposites of polypropylene and graphene nanoplatelets were synthesized by in situ polymerization in liquid monomer in the presence of highly effective isospecific homogeneous metallocene catalyst. Microstructure, mechanical, dielectric, and thermal properties of composites are presented. X-ray phase analysis data indicate that graphene nanoplatelets are present in composites as thin flaky particles aggregates, with aspect ratio affected by sonication of reaction mixture. Crystallization temperature of polypropylene increases in composites. Nanocomposites are characterized by high rigidity, thermal stability, and crystallization temperature, low conductivity, and high dielectric losses in the microwave range. (C) 2012 Wiley Periodicals, Inc. J. Appl. Polym. Sci., 2013