• 文献标题:   Simultaneous electrochemical detection of Cd and Pb in aquatic samples via coupled graphene with brominated white polyaniline flakes
  • 文献类型:   Article
  • 作  者:   HASHEMI SA, BAHRANI S, MOUSAVI SM, OMIDIFAR N, ARJMAND M, LANKARANI KB, RAMAKRISHNA S
  • 作者关键词:   sensor, cadmium, lead, white polyaniline, graphene
  • 出版物名称:   EUROPEAN POLYMER JOURNAL
  • ISSN:   0014-3057 EI 1873-1945
  • 通讯作者地址:  
  • 被引频次:   14
  • DOI:   10.1016/j.eurpolymj.2021.110926 EA DEC 2021
  • 出版年:   2022

▎ 摘  要

Severe toxicity of heavy metal ions and their adverse effects on the ecosystem and health of living species raised a requirement to develop practical detection configurations capable of simultaneous and differentiable detection of toxic metal ions in aquatic samples. In this regard, we have fabricated a high-performance sensor configuration based on the integrated reduced graphene oxide (rGO) flakes with brominated white polyaniline (PANi) flakes toward the prompt and accurate detection of Pb (II) and Cd (II) in biological and non-biological specimens. The as-developed configuration simultaneously identified both Pb (II) and Cd (II) through a differentiable manner with a limit of detection (LOD)/quantification limit (QL) of 7.3 nM/85 nM and 6.5 nM/92 nM, respectively. The sensor also showed superior sensitivity of about 4547.77 and 3914.01 mu A.mu M-1.cm(-2) toward Pb (II) and Cd (II), respectively, along with a favorable recovery rate in actual human blood plasma and wastewater samples. The asdeveloped complex proved to be an ideal platform for simultaneous detection/recovery of heavy metal ions in various aquatic samples.