• 文献标题:   Enhancement of the Photocatalytic Oxygen Production by Tantalum Nitride Supported Fe Atom Embedded N-Doped Graphene Oxide
  • 文献类型:   Article
  • 作  者:   CHEN HX, YAN J, MO Z, LIU JY, ZHU XL, LI HM, XU H
  • 作者关键词:   photocatalysi, electron transfer, fe atom embedded ndoped graphene oxide, ta3n5, catalysi
  • 出版物名称:   CHINESE JOURNAL OF CHEMISTRY
  • ISSN:   1001-604X EI 1614-7065
  • 通讯作者地址:  
  • 被引频次:   0
  • DOI:   10.1002/cjoc.202200337 EA DEC 2022
  • 出版年:   2023

▎ 摘  要

Energy crises and environmental pollution have become urgent problems with human civilization development. Photocatalysis technology is a green method to deal with these challenges. The key to improve photocatalytic efficiency lies in the effective separation of photogenerated electron-hole pairs. In this work, we designed the Fe atom embedded N-doped graphene oxide (Fe-NGO) supporting on tantalum nitride (Ta3N5) catalyst, which was employed to improve the photocatalytic oxygen production activity. The oxygen production of 5 wt% Fe atom embedded N-doped graphene oxide supporting on tantalum nitride (Fe-NGO/Ta3N5) was 184.7 mu molmiddotg(-1), about 3.5 times higher than that of the pure Ta3N5. The introduction of the cocatalyst Fe-NGO acting as an electron conductor in the Fe-NGO/Ta3N5 accelerates the carrier migration of Ta3N5 and further enhances the photocatalytic oxygen production activity. N-doping increases the conductivity of graphene oxide (GO), and Fe atoms are used as the reactive sites to promote the combination of electron and sacrificial agent in the system. This work may provide insights into the research of new carbon cocatalyst materials.