▎ 摘 要
C-60 treatment at 5-8 GPa, similar to 1000 degrees C results in the fullerene cage collapse and transformation to a phase with outstanding mechanical properties. A detailed structural analysis of the phase reveals that it comprised 7-12 layer graphene clusters with lateral dimension of 2-4 nm. Raman spectra of the nanoclustered graphene phase are similar to those of disordered sp(2) carbon structure with an admixture of sp(3)-bonded carbon. The phase is characterized by a high (up to 19 GPa) hardness, relatively low (about 70 GPa) Young modulus and up to 95% elastic recovery, determining excellent wear resistance and good antifriction properties. (C) 2014 AIP Publishing LLC.