• 文献标题:   Structure and physical properties of nanoclustered graphene synthesized from C-60 fullerene under high pressure and high temperature
  • 文献类型:   Article
  • 作  者:   CHERNOGOROVA O, POTAPOVA I, DROZDOVA E, SIROTINKIN V, SOLDATOV AV, VASILIEV A, EKIMOV E
  • 作者关键词:  
  • 出版物名称:   APPLIED PHYSICS LETTERS
  • ISSN:   0003-6951 EI 1077-3118
  • 通讯作者地址:   AA Baikov Inst Met Mat Sci IMET
  • 被引频次:   12
  • DOI:   10.1063/1.4863470
  • 出版年:   2014

▎ 摘  要

C-60 treatment at 5-8 GPa, similar to 1000 degrees C results in the fullerene cage collapse and transformation to a phase with outstanding mechanical properties. A detailed structural analysis of the phase reveals that it comprised 7-12 layer graphene clusters with lateral dimension of 2-4 nm. Raman spectra of the nanoclustered graphene phase are similar to those of disordered sp(2) carbon structure with an admixture of sp(3)-bonded carbon. The phase is characterized by a high (up to 19 GPa) hardness, relatively low (about 70 GPa) Young modulus and up to 95% elastic recovery, determining excellent wear resistance and good antifriction properties. (C) 2014 AIP Publishing LLC.