• 文献标题:   Few-layer Graphene Lithiophilic and Sodiophilic Diffusion Layer on Porous Stainless Steel as Lithium and Sodium Metal Anodes
  • 文献类型:   Article
  • 作  者:   PATRIKE A, WASNIK K, SHELKE MV
  • 作者关键词:   freestanding, few layer graphene, li na metal functional host, postcycling xps, na depth profile
  • 出版物名称:   CHEMISTRYAN ASIAN JOURNAL
  • ISSN:   1861-4728 EI 1861-471X
  • 通讯作者地址:  
  • 被引频次:   0
  • DOI:   10.1002/asia.202300068 EA MAR 2023
  • 出版年:   2023

▎ 摘  要

In order to subdue the obvious problem of uneven electric field distribution on regularly used copper/aluminum current collectors for alkali metal batteries, graphene on porous stainless steel (pSS_Gr) was fabricated using the ion etching technique that is employed as an effective host for lithium and sodium metal anodes. The binder-free pSS_Gr demonstrated stable Li plating and stripping at areal current and capacity of 6 mA cm(-2) and 2.54 mAh cm(-2), respectively, for over 1000 cycles with 98% coulombic efficiency (C.E.). Also, in the case of Na metal anode, the host has shown stable performance at 4 mA cm(-2) and 1 mAh cm(-2) over 1000 cycles with similar to 100% C.E.. Further, a full cell composed of Li-plated pSS_Gr as an anode and LiFePO4 as a cathode is electrochemically tested at 50 mA g(-1) current density with stable 100 cycles.